i need some informations about hydrogen sulfide..

Wed, Oct 12 2011 10:40am IST 1
Shinta Herlianty
Shinta Herlianty
1 Posts

Dear everybody,

could you give me some informations and file about hydrogen sulfide in the oil and gas industry mainly in refinery oil and gas? (including regulatory, impacts to workers, processing and management hydrogen sulfide gas) thank you ..

Regard,

SHINTA HERLIANTY

Wed, Oct 12 2011 12:10pm IST 2
Richard Brown
Richard Brown
141 Posts
There are many health & safety issues relating to Hydrogen Sulphide:
1. Human toxicity (fatal accidents)
2. Corrosion of steel (Asset integrity)
3. Hydrogen embrittlement (Asset integrity)
4. Formation of Pyrophoric Scale (Fire/explosion risk)
5. Sulphur dioxide production when flaring sour gas (Environmental pollution)
6. Safe storage of sulphur produced during desulphurisation of oil & gas (Fire risk)

References:
Health & Safety Executive (UK)
Safety aspects of the effects of hydrogen sulphide concentrations in natural gas
Managing Hydrogen Sulphide Detection Offshore
Hazardous Area Classification & Control of Ignition Sources
Grangemouth Refinery fire
Hydrogen Sulphide Embrittlement of Steels

Health Protection Agency (UK)
Hydrogen Sulphide

OSHA (US)
Hydrogen Sulphide Fact Sheet
Oil & Gas Well Drilling eTool

NIOSH (US)
Hydrogen Sulphide

WHO (International)
Hydrogen Sulphide

ILO (International)
International Chemical Safety Card - Hydrogen Sulphide

Energy Institute
Safety in refinery and chemical plant operations

Chevron
Pyrophoric Scale

Miscellaneous Sources
Pyrophoric Iron Fires

Hope this helps - it is a very big topic

Regards

Richard Brown

Thu, Oct 13 2011 07:31am IST 3
suriya prakash
suriya prakash
2 Posts
Hydrogen Sulfide (H2S) Awareness PDF E-mail

Hydrogen sulfide is a colorless, flammable, extremely hazardous gas with a “rotten egg” smell. It occurs naturally in crude petroleum and natural gas, and can be produced by the breakdown of organic matter and human/animal wastes (e.g., sewage). It is heavier than air and can collect in low-lying and enclosed, poorly ventilated areas such as basements, manholes, sewer lines and underground telephone/electrical vaults.

DETECTION BY SMELL

  • Can be smelled at low levels, but with continuous low-level exposure or at higher concentrations you lose your ability to smell the gas even though it is still present.

  • At high concentrations your ability to smell the gas can be lost instantly.

  • DO NOT depend on your sense of smell for indicating the continuing presence of this gas or for warning of hazardous concentrations.

HEALTH EFFECTS

Health effects vary with how long, and at what level, you are exposed. Asthmatics may be at greater risk.

  • Low concentrations – irritation of eyes, nose, throat, or respiratory system; effects can be delayed.

  • Moderate concentrations – more severe eye and respiratory effects, headache, dizziness, nausea, coughing, vomiting and difficulty breathing.

  • High concentrations – shock, convulsions, unable to breathe, coma, death; effects can be extremely rapid (within a few breaths).

BEFORE ENTERING AREAS WITH POSSIBLE HYDROGEN SULFIDE

  • The air needs to be tested for the presence and concentration of hydrogen sulfide by a qualified person using test equipment. This individual also determines if fire/explosion precautions are necessary.

  • If gas is present, the space should be ventilated.

  • If the gas cannot be removed, use appropriate respiratory protection and any other necessary personal protective equipment (PPE), rescue and communication equipment. Atmospheres containing high concentrations (greater than 100 ppm) are considered immediately dangerous to life and health (IDLH) and a self-contained breathing apparatus (SCBA) is required.


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